• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A novel compound for combatting insect, mite, fungus or bacterium is a pyridylaniline represented by the following formula (I) wherein X is a trifluoromethyl group, a halogen atom, a lower alkyl group or a lower alkoxy group; n is an integer of 0 to 4; R is a hydrogen atom or an acetyl group; Y is a hydrogen atom, a halogen atom a lower alkoxy group, a lower alkylthio group, a hydroxy group, an azido group or a phenoxy group of which the phenyl ring may be substituted by a hydroxy group; Z1,Z2 and Z3 are a trifluoromethyl group or a nitro group, provided that at least one of X is a trifluoromethyl group or a lower alkyl group when n is an integer of 3 or 4.
    公开号:SU1431660A3
    申请号:SU803222449
    申请日:1980-12-24
    公开日:1988-10-15
    发明作者:Нисийяма Риуцо；Фуикава Каничи；Нага Такахиро；Токи Тадааки；Нагатани Кунияки；Имаи Осаму
    申请人:Исихара Самгио Кайся Лтд (Фирма)；
    IPC主号:
    专利说明:

    This invention relates to Kim # 1 ™ CIM plant protection products, specifically to a fungicidal agent in the form of a wetting powder based on a derivative of pyrikanylanin 5 silica and the product of condensation of ethylene oxide with nonylphenol.
    The purpose of the invention is to increase the fungicidal activity of the agent.
    Pyridinyl alcohol derivatives of the formula
    Xp 92 Y (I)
    N
    in which 5 when the pyridine ring is substituted by aniline in position 2 when Y is hydrogen 5 if n 2j then X is chlorine in position 3 and 5, and if a and p 3} then X is chlorine in position 6, bromine in position 5 and trifluoromethyl in position 3s with Y is chlorine, if n is 2, then X is chlorine in position 3 and 5 P1I is chlorine in position 3 and trifluoromethyl is in position 5s, and if n is 3, then X is chlorine bromine trnfluoromethyl, methyl, provided that two radicals X mean halogen one of which is xhopj when the pyridine ring is substituted with aniline at position 3, then Y is glueless, n 2, X is chlorine at position 2 and 6 is obtained by reacting with Unity - formula (II) with the compound of the formula (III)
    РN
    (AND)
    u-fwcho -cFz- - -40
    V.
    BUT
    N02
    , (.N
    where Xs Y and n have the indicated meanings; and and W are respectively a halogen atom or an amino group, moreover, in the case when U is an amino group, W is a halogen atom, preferably the reaction is carried out between compound (II), in which U is an amino group, and compound (III), in which W is a halogen atom about
    0
    five
    0
    five
    five
    0
    0
    five
    0
    five
    The reaction is carried out in an aprotic polar solvent at a temperature of (-100) to (+ 200) C, preferably from 0 ° C to within 0.5 to 24 hours.
    Thus, the compounds (I) obtained are presented in table. one.
    The proposed fungicidal agents in the form of a wettable powder are obtained by mixing the components until a homogeneous mixture is formed, followed by grinding to a powder. Thus receive the funds presented in table. 2
    The following examples illustrate the high fungicidal activity of the proposed agents in comparison with the known containing as a-. the active ingredient of the compound of formula
    C1 F SGS
    (OVN02 (A)) - C1 F
    Example 1. A mixture of 9 ml of potato-glucose agar medium and 1 ml of the solution of means 1 is poured into a Petri dish. On the agar disks thus obtained, various fungal organisms are cultivated and placed for several days in thermostatic conditions to maintain the optimum temperature. What is the growth of mycelium evaluated and the minimum inhibitory growth of fungi of the active ingredient of agent I is determined. In this test series, the following fungi are used:
    A: Phytophthora infestans
    B; Diaporthe citri
    C: Alternaria solani
    D: Venturia inaegualie
    The results are presented in Table. 3,
    Example 2. Clay unglazed pods with a diameter of 9 cm grow cucumber seedlings. At the single leaf growth stage, the sprouts are sprayed from a sprayer-sprayer with 10 ml (per pot) of the solution prepared from each powder — Mdro products and having an active ingredient concentration of 0.05%. After the pots are kept in the greenhouse, at 24--25 ° C for 1 h, the seedlings in each pot are sprayed with suspension
    dispute culture Collectotrichum lagena- rium. 6 days after the plants are infected, they are visually inspected and the number of transformations is assessed.
    the first leaf on the seedlings. Based on the data obtained, a protective index is calculated using the formula
    Protective index
    权利要求:
    Claims (1)
    [1]
    1 Data are presented in table. 4. The invention formula
    A fungicide agent in the form of a wetting powder, containing the active ingredient a pyrvdinilaniline derivative, a carrier silica and a surfactant, characterized in that, in order to increase the fungicidal activity, it contains as a pyridinylniline derivative a compound of the formula
    Y Uo I r. P1 /
    CQj-NH- y-CFj 02 in which, when the pyridine ring 35 is substituted with aniline in position 2, with
    damage number first
    leaflet in the treated pots.
    the number of damage to the first fox- / point in untreated pot- / kah
    five
    0
    five
    0
    five
    Y is hydrogen, if n is 2, then X is chlorine in position 3 and 5, and if n is 3, then X is chlorine in position 6, bromine is in position 5 and trifluoromethyl is in position 3, with Y is chlorine, if n is 2, then X is chlorine in position 3 and 5 or chlorine in position 3 and trifluoromethyl in position 5, and if n is 3, then X is chlorine, bromine, trifluoromethyl, methyl, provided that two radicals X mean halogen, and one of chlorine, when the pyridine ring is replaced by aniline in position 3, then Y is chlorine, n 2, and X is chlorine in position 2 and 6, and as a surfactant is simple polyoxyethylene n sulfate, nonylphenyl ether Fira, in the following ratio of components, May.%:
    Active ingredient 5-70 Carrier 20-92,5
    Surfactant 2,5-10 I
    Table 1
    Table 4
    类似技术:
    公开号 | 公开日 | 专利标题
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    AU605774B2|1991-01-24|Imidazole derivatives, their preparation and their use as fungicides
    US4049820A|1977-09-20|Substituted urazole and thiourazole compounds as agricultural fungicidal agents
    SU784732A3|1980-11-30|Fungicidic composition
    US4405743A|1983-09-20|Pyrazolylpyrimidine derivatives
    EP0123931A2|1984-11-07|Furan derivatives having fungicide activity
    US3651088A|1972-03-21|Certain anilinoalkyl mercaptans as fungicides
    EP0412681B1|1994-09-28|Azolidine derivatives, process for preparing the same and agricultural and horticultural fungicide
    同族专利:
    公开号 | 公开日
    PL228754A1|1981-09-04|
    ES8205776A1|1982-07-01|
    AR228582A1|1983-03-30|
    JPS5692272A|1981-07-25|
    UA6317A1|1994-12-29|
    BR8008501A|1981-07-21|
    PL125887B1|1983-06-30|
    EP0031257B1|1984-08-15|
    ES498055A0|1982-07-01|
    NL971017I2|1998-01-05|
    EP0031257A3|1981-11-18|
    US4331670A|1982-05-25|
    HU185231B|1984-12-28|
    NL971017I1|1997-09-01|
    MY8700889A|1987-12-31|
    JPS6052146B2|1985-11-18|
    EP0031257A2|1981-07-01|
    DE3068979D1|1984-09-20|
    DD155713A5|1982-06-30|
    引用文献:
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP54168574A|JPS6052146B2|1979-12-25|1979-12-25|LTRP480A| LT2077B|1979-12-25|1993-04-07|FUNGICIDINE MATERIAL IN DEGREE POWDER|
    LV930266A| LV5652A3|1979-12-25|1993-04-23|Powdery Fungicide ipasibam Powdery Surface Moisturizer|
    MD94-0019A| MD37C2|1979-12-25|1993-12-07|Fungicidal agent in the form of a wettable powder|
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